PROBLEM
1. The pH of a 6.81×10−2M solution of a weak monoprotic acid is 5.28 . Calculate the percent dissociation of the acid to 3 significant figures.
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STEP 1
1. The solution is of a weak monoprotic acid.
2. The concentration of the acid is 6.81×10−2M.
3. The pH of the solution is 5.28.
4. We need to calculate the percent dissociation of the acid to 3 significant figures.
STEP 2
1. Calculate the concentration of hydrogen ions [H+] using the pH.
2. Determine the initial concentration of the acid.
3. Calculate the percent dissociation of the acid.
STEP 3
Calculate the concentration of hydrogen ions [H+] using the pH.
The formula to find the concentration of hydrogen ions from pH is:
pH=−log10[H+] Rearrange to find [H+]:
[H+]=10−pH Substitute the given pH value:
[H+]=10−5.28 Calculate [H+]:
[H+]≈5.25×10−6M
STEP 4
Determine the initial concentration of the acid, which is given as:
[Acid]0=6.81×10−2M
SOLUTION
Calculate the percent dissociation of the acid.
Percent dissociation is given by the formula:
Percent Dissociation=([Acid]0[H+])×100% Substitute the values:
Percent Dissociation=(6.81×10−25.25×10−6)×100% Calculate the percent dissociation:
Percent Dissociation≈0.00771% Round to 3 significant figures:
Percent Dissociation≈0.00771%
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