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PROBLEM

1. The pH of a 6.81×102M6.81 \times 10^{-2} \mathrm{M} solution of a weak monoprotic acid is 5.28 . Calculate the percent dissociation of the acid to 3 significant figures.
\%
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STEP 1

1. The solution is of a weak monoprotic acid.
2. The concentration of the acid is 6.81×102M 6.81 \times 10^{-2} \mathrm{M} .
3. The pH of the solution is 5.28.
4. We need to calculate the percent dissociation of the acid to 3 significant figures.

STEP 2

1. Calculate the concentration of hydrogen ions [H+][\mathrm{H}^+] using the pH.
2. Determine the initial concentration of the acid.
3. Calculate the percent dissociation of the acid.

STEP 3

Calculate the concentration of hydrogen ions [H+][\mathrm{H}^+] using the pH.
The formula to find the concentration of hydrogen ions from pH is:
pH=log10[H+] \mathrm{pH} = -\log_{10}[\mathrm{H}^+] Rearrange to find [H+][\mathrm{H}^+]:
[H+]=10pH [\mathrm{H}^+] = 10^{-\mathrm{pH}} Substitute the given pH value:
[H+]=105.28 [\mathrm{H}^+] = 10^{-5.28} Calculate [H+][\mathrm{H}^+]:
[H+]5.25×106M [\mathrm{H}^+] \approx 5.25 \times 10^{-6} \mathrm{M}

STEP 4

Determine the initial concentration of the acid, which is given as:
[Acid]0=6.81×102M [\text{Acid}]_0 = 6.81 \times 10^{-2} \mathrm{M}

SOLUTION

Calculate the percent dissociation of the acid.
Percent dissociation is given by the formula:
Percent Dissociation=([H+][Acid]0)×100% \text{Percent Dissociation} = \left( \frac{[\mathrm{H}^+]}{[\text{Acid}]_0} \right) \times 100\% Substitute the values:
Percent Dissociation=(5.25×1066.81×102)×100% \text{Percent Dissociation} = \left( \frac{5.25 \times 10^{-6}}{6.81 \times 10^{-2}} \right) \times 100\% Calculate the percent dissociation:
Percent Dissociation0.00771% \text{Percent Dissociation} \approx 0.00771\% Round to 3 significant figures:
Percent Dissociation0.00771% \text{Percent Dissociation} \approx 0.00771\%

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