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PROBLEM

11) 0.7515 moles of nitrogen gas and 0.1135 moles of methane gas are placed in a 171.6 ml container at 20.8C20.8^{\circ} \mathrm{C}. What is the partial pressure (atm) of nitrogen gas?
A) 1.14
B) 0.473
C) 16.0
D) 106
E) 226

STEP 1

1. We are given the moles of nitrogen gas and methane gas.
2. The volume of the container is 171.6 ml.
3. The temperature is given as 20.8C20.8^{\circ} \mathrm{C}.
4. We need to find the partial pressure of nitrogen gas in atm.
5. We will use the ideal gas law to find the partial pressure.

STEP 2

1. Convert the volume from ml to liters.
2. Convert the temperature from Celsius to Kelvin.
3. Use the ideal gas law to calculate the partial pressure of nitrogen gas.

STEP 3

Convert the volume from ml to liters.
Volume in liters=171.6ml1000=0.1716L \text{Volume in liters} = \frac{171.6 \, \text{ml}}{1000} = 0.1716 \, \text{L}

STEP 4

Convert the temperature from Celsius to Kelvin.
Temperature in Kelvin=20.8+273.15=293.95K \text{Temperature in Kelvin} = 20.8 + 273.15 = 293.95 \, \text{K}

SOLUTION

Use the ideal gas law to calculate the partial pressure of nitrogen gas. The ideal gas law is given by:
PV=nRT PV = nRT Where:
- P P is the pressure,
- V V is the volume,
- n n is the number of moles,
- R R is the ideal gas constant (0.0821L atm/mol K0.0821 \, \text{L atm/mol K}),
- T T is the temperature in Kelvin.
Rearrange the formula to solve for P P :
P=nRTV P = \frac{nRT}{V} Substitute the values for nitrogen gas:
P=0.7515moles×0.0821L atm/mol K×293.95K0.1716L P = \frac{0.7515 \, \text{moles} \times 0.0821 \, \text{L atm/mol K} \times 293.95 \, \text{K}}{0.1716 \, \text{L}} Calculate the partial pressure:
P=0.7515×0.0821×293.950.1716 P = \frac{0.7515 \times 0.0821 \times 293.95}{0.1716} P18.1080.1716 P \approx \frac{18.108}{0.1716} P105.55atm P \approx 105.55 \, \text{atm} The closest answer choice is:
106 \boxed{106}

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