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Math

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PROBLEM

(a) The [H+]\left[\mathrm{H}^{+}\right]of a solution is 2.7×1062.7 \times 10^{-6} Calculate the pH .
(b) The [OH]\left[\mathrm{OH}^{-}\right]of a solution is 3.2×1083.2 \times 10^{-8} Calculate the pOH .
(c) The [H+]\left[\mathrm{H}^{+}\right]of a solution is 5.4×1035.4 \times 10^{-3} Calculate the [OH]\left[\mathrm{OH}^{-}\right].
(d) The [OH]\left[\mathrm{OH}^{-}\right]of a solution is 1.8×1091.8 \times 10^{-9} Calculate the [H+]\left[\mathrm{H}^{+}\right].

STEP 1

What is this asking?
We need to calculate pH, pOH, and concentrations of hydrogen and hydroxide ions given some initial values.
Watch out!
Don't mix up pH\text{pH} and pOH\text{pOH}, and remember those negative exponents!

STEP 2

1. Calculate pH
2. Calculate pOH
3. Calculate hydroxide ion concentration
4. Calculate hydrogen ion concentration

STEP 3

Alright, let's start with calculating the pH\text{pH}!
We're given that the hydrogen ion concentration, [H+][\text{H}^{+}], is 2.71062.7 \cdot 10^{-6}.

STEP 4

Remember, the formula for pH\text{pH} is pH=log10([H+])\text{pH} = -\log_{10}([\text{H}^{+}]).
Let's plug in our given value:
pH=log10(2.7106) \text{pH} = -\log_{10}(2.7 \cdot 10^{-6})

STEP 5

Now, we evaluate the logarithm:
pH(5.57) \text{pH} \approx -(-5.57)

STEP 6

So, our pH\text{pH} is:
pH5.57 \text{pH} \approx 5.57

STEP 7

Next up, we're given that the hydroxide ion concentration, [OH][\text{OH}^{-}], is 3.21083.2 \cdot 10^{-8}.
The formula for pOH\text{pOH} is pOH=log10([OH])\text{pOH} = -\log_{10}([\text{OH}^{-}]).

STEP 8

Let's plug in our value:
pOH=log10(3.2108) \text{pOH} = -\log_{10}(3.2 \cdot 10^{-8})

STEP 9

Evaluating the logarithm gives us:
pOH(7.49) \text{pOH} \approx -(-7.49)

STEP 10

Therefore, the pOH\text{pOH} is:
pOH7.49 \text{pOH} \approx 7.49

STEP 11

Now, we're given [H+]=5.4103[\text{H}^{+}] = 5.4 \cdot 10^{-3} and we need to find [OH][\text{OH}^{-}].
Remember the key relationship: [H+][OH]=1.01014[\text{H}^{+}] \cdot [\text{OH}^{-}] = 1.0 \cdot 10^{-14}.

STEP 12

Let's solve for [OH][\text{OH}^{-}]:
[OH]=1.01014[H+] [\text{OH}^{-}] = \frac{1.0 \cdot 10^{-14}}{[\text{H}^{+}]}

STEP 13

Substitute the given value of [H+][\text{H}^{+}]:
[OH]=1.010145.4103 [\text{OH}^{-}] = \frac{1.0 \cdot 10^{-14}}{5.4 \cdot 10^{-3}}

STEP 14

Calculating the result:
[OH]1.851012 [\text{OH}^{-}] \approx 1.85 \cdot 10^{-12}

STEP 15

Finally, we're given [OH]=1.8109[\text{OH}^{-}] = 1.8 \cdot 10^{-9} and we need to find [H+][\text{H}^{+}].
We'll use the same relationship as before: [H+][OH]=1.01014[\text{H}^{+}] \cdot [\text{OH}^{-}] = 1.0 \cdot 10^{-14}.

STEP 16

Solving for [H+][\text{H}^{+}]:
[H+]=1.01014[OH] [\text{H}^{+}] = \frac{1.0 \cdot 10^{-14}}{[\text{OH}^{-}]}

STEP 17

Substituting the given value of [OH][\text{OH}^{-}]:
[H+]=1.010141.8109 [\text{H}^{+}] = \frac{1.0 \cdot 10^{-14}}{1.8 \cdot 10^{-9}}

STEP 18

Calculating the result:
[H+]5.56106 [\text{H}^{+}] \approx 5.56 \cdot 10^{-6}

SOLUTION

(a) pH5.57\text{pH} \approx 5.57
(b) pOH7.49\text{pOH} \approx 7.49
(c) [OH]1.851012[\text{OH}^{-}] \approx 1.85 \cdot 10^{-12}
(d) [H+]5.56106[\text{H}^{+}] \approx 5.56 \cdot 10^{-6}

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