PROBLEM
Antimony has isotopes 121Sb (120.9038 u) and 123Sb (122.9042 u). Find their percent abundances.
STEP 1
Assumptions1. Antimony has two naturally occurring isotopes, 121b and 123b.
. The atomic mass of 121b is 120.9038u.
3. The atomic mass of 123b is 122.904u.
4. The average atomic mass of Antimony is 121.7601u.
5. The sum of the percent natural abundances of the two isotopes is100%.
STEP 2
Let's denote the percent natural abundance of 121b as x and that of 123b as y. From assumption5, we have the following equationx+y=100
STEP 3
The average atomic mass of Antimony is a weighted average of the atomic masses of its isotopes, with the weights being their percent natural abundances. This gives us the following equation120.9038x+122.9042y=121.7601×100
STEP 4
We now have a system of two equations, which we can solve to find the values of x and y.
{x+y=100120.9038x+122.9042y=121.7601×100
STEP 5
Let's first solve the second equation for x.
x=120.9038121.7601×100−122.9042y
STEP 6
Now, substitute the value of x from the second equation into the first equation.
120.9038121.7601×100−122.9042y+y=100
STEP 7
olve this equation for y.
y=122.9042−120.903121.7601×100−120.903×100
STEP 8
Calculate the value of y.
y=122.9042−120.9038121.7601×100−120.9038×100≈57.36
STEP 9
Now, substitute the value of y into the first equation to find the value of x.
x=100−y
SOLUTION
Calculate the value of x.
x=100−57.36=42.64The percent natural abundance of 121b is approximately42.64% and that of 123b is approximately57.36%.
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