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PROBLEM

\text{How much heat is produced when 74 grams of Al react in the following reaction?} \\ 2 \mathrm{Al}(s) + \mathrm{Fe}_{2} \mathrm{O}_{3}(s) \rightarrow 2 \mathrm{Fe}(s) + \mathrm{Al}_{2} \mathrm{O}_{3}(s) \\ \text{Heat of reaction} = -851.5 \, \mathrm{kJ} \\

STEP 1

1. The balanced chemical equation is 2Al(s)+Fe2O3(s)2Fe(s)+Al2O3(s)2 \text{Al}(s) + \text{Fe}_2\text{O}_3(s) \rightarrow 2 \text{Fe}(s) + \text{Al}_2\text{O}_3(s).
2. The heat of reaction is 851.5kJ-851.5 \, \text{kJ}.
3. We are given 74 grams of aluminum (Al\text{Al}).
4. We need to calculate the heat produced when 74 grams of Al\text{Al} react.

STEP 2

1. Calculate the molar mass of aluminum.
2. Determine the number of moles of aluminum in 74 grams.
3. Use stoichiometry to find the heat produced.

STEP 3

Calculate the molar mass of aluminum (Al\text{Al}).
The atomic mass of aluminum is approximately 26.98g/mol26.98 \, \text{g/mol}.

STEP 4

Determine the number of moles of aluminum in 74 grams.
Use the formula:
Number of moles=massmolar mass\text{Number of moles} = \frac{\text{mass}}{\text{molar mass}} Substitute the known values:
Number of moles of Al=74g26.98g/mol2.74mol\text{Number of moles of Al} = \frac{74 \, \text{g}}{26.98 \, \text{g/mol}} \approx 2.74 \, \text{mol}

SOLUTION

Use stoichiometry to find the heat produced.
According to the balanced equation, 2 moles of Al\text{Al} produce 851.5kJ-851.5 \, \text{kJ} of heat.
Calculate the heat produced for 2.74 moles of Al\text{Al}:
Heat produced=(851.5kJ2mol)×2.74mol\text{Heat produced} = \left(\frac{-851.5 \, \text{kJ}}{2 \, \text{mol}}\right) \times 2.74 \, \text{mol} Heat produced1166.5kJ\text{Heat produced} \approx -1166.5 \, \text{kJ} The heat produced when 74 grams of aluminum react is approximately 1166.5kJ-1166.5 \, \text{kJ}.

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